
University of Manchester scientists open up a new range of opportunities for the world’s thinnest material in the area of spintronics.The results, reported in Science, could make for a huge breakthrough in the field of spintronics.
Findings are part of a large international effort involving US, Russia, Japan and the Netherlands research groups.
Key feature for spintronics is to connect the electron spin to electric current as current can be manipulated by means routinely used in microelectronics.
It is thought that, in future spintronics devices and transistors, coupling between the current and spin will be direct, without using magnetic materials to inject spins as it is done at the moment.
But this route has only been demonstrated by using materials with so-called spin-orbit interaction, in which tiny magnetic fields created by nuclei affect the motion of electrons through a crystal. The effect is generally small which makes it difficult to use.
The researchers found a new way to interconnect spin and charge by applying a relatively weak magnetic field to graphene and found that this causes a flow of spins in the direction perpendicular to electric current, making a graphene sheet magnetised.
The effect resembles the one caused by spin-orbit interaction but is larger and can be tuned by varying the external magnetic field.
The Manchester researchers also show graphene placed on boron nitride is an ideal material for spintronics as the induced magnetism extends over macroscopic distances from the current path without decay.
The team believes their discovery offers numerous opportunities for redesign of current spintronics devices and making new ones such as spin-based transistors.
Professor Geim said: “The holy grail of spintronics is the
conversion of electricity into magnetism or vice versa.
“We offer a new mechanism, thanks to unique properties of graphene. I imagine that many venues of spintronics can benefit from this finding.”
Antonio Castro Neto, a physics professor from Boston who wrote a news article which accompanies the research paper commented: “Graphene is opening doors for many new technologies. Not surprisingly, the 2010 Nobel Physics prize was awarded to Andre Geim and Kostya Novoselov for their groundbreaking experiments in this material.
“Apparently not satisfied with what they have accomplished so far, Geim and his collaborators have now demonstrated another completely unexpected effect that involves quantum mechanics at ambient conditions. This discovery opens a new chapter to the short but rich history of graphene”.
Tunable Kondo effects
University of Maryland researchers have discovered a way to control magnetic properties of graphene that could lead to powerful new applications in magnetic storage and MRAM.
Led by Physics Professor Michael S. Fuhrer (left) of the
UMD Center for Nanophysics and Advanced Materials is the latest of many amazing properties found in graphene.
A honeycomb sheet of carbon atoms just one atom thick, graphene is the basic constituent of graphite. Some 200 times stronger than steel, it conducts electricity at room temperature better than any other known material (a 2008 discovery by Fuhrer, et. al). Graphene is widely seen as having great, perhaps even revolutionary, potential for nanotechnology applications.
In their graphene discovery, Fuhrer and his University of Maryland colleagues have found that missing atoms in graphene, called vacancies, act as tiny magnets - having a "magnetic moment." These magnetic moments interact strongly with electrons in graphene which carry electrical currents, giving rise to a significant extra electrical resistance at low temperature, known as the Kondo effect.
Results appear in the paper "Tunable Kondo effect in
graphene with defects" published in Nature Physics (Right)
The Kondo effect is typically associated with adding tiny amounts of magnetic metal atoms, such as iron or nickel, to a non-magnetic metal, such as gold or copper. Finding the Kondo effect in graphene with vacancies was surprising for two reasons, according to Fuhrer.
"First, we were studying a system of nothing but carbon, without adding any traditionally magnetic impurities. Second, graphene has a very small electron density, which would be expected to make the Kondo effect appear only at extremely low temperatures," he said.
The team measured the characteristic temperature for the Kondo effect in graphene with vacancies to be as high as 90 Kelvin, which is comparable to that seen in metals with very high electron densities. Kondo temperature can be tuned by the voltage on an electrical gate, an effect not seen in metals.
They theorize that the same unusual properties of that result in graphene's electrons acting as if they have no mass also make them interact very strongly with certain kinds of impurities, such as vacancies, leading to a strong Kondo effect at a relatively high temperature.
Fuhrer thinks that if vacancies in graphene could be arranged in just the right way, ferromagnetism could result. "Individual magnetic moments can be coupled together through the Kondo effect, forcing them all to line up in the same direction," he said.
"The result would be a ferromagnet, like iron, but instead made only of carbon. Magnetism in graphene could lead to new types of nanoscale sensors of magnetic fields. Coupled with graphene's electrical properties, magnetism in graphene could also have interesting applications in the area of spintronics.
"This opens the possibility of 'defect engineering' in graphene - plucking out atoms in the right places to design the magnetic properties you want," said Fuhrer.